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Title: A fine tuning of metallaborane to bridged-boryl complex, [(Cp*Ru)2(μ-H)(μ-CO)(μ-Bcat)] (cat = 1,2-O2C6H4; Cp* = η5-C5Me5)
Authors: Anju, R.S.
Roy, D.K.
Geetharani, K.
Mondal, B.
Varghese, B.
Ghosh, S.
Keywords: X ray diffraction
Fine tuning
Room temperature
Issue Date: 2013
Publisher: Royal Society of Chemistry
Citation: Dalton Transactions, 42(36), 12828-12831
Abstract: Room temperature photolysis of [(Cp*RuCO)<inf>2</inf>BH <inf>4</inf>(Bcat)], 3, generated from the reaction of arachno-[(Cp*RuCO) <inf>2</inf>B<inf>2</inf>H<inf>6</inf>], 1, with HBcat (cat = 1,2-O <inf>2</inf>C<inf>6</inf>H<inf>4</inf>), yielded a rare homodinuclear bridged-boryl complex, [(Cp*Ru)<inf>2</inf>(?-H)(?-CO)(?-Bcat)], 4, confirmed by X-ray diffraction.
ISSN: 14779226
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