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|Title:||Facile base-free in situ generation and palladation of mesoionic and normal N-heterocyclic carbenes at ambient conditions|
|Keywords:||Palladation of meso-ionic|
|Publisher:||Royal Society of Chemistry|
|Citation:||Dalton Transactions, 43(28), 10710-10712|
|Abstract:||Synthesis of normal and mesoionic N-heterocyclic carbene Pd(ii) complexes in near quantitative yields from the corresponding NHC precursor salts under base free and ambient conditions is reported. A plausible mechanism involving charge-assisted hydrogen bonded intermediates is proposed.|
|Appears in Collections:||Articles|
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