Please use this identifier to cite or link to this item: http://hdl.handle.net/11717/15515
Title: Facile base-free in situ generation and palladation of mesoionic and normal N-heterocyclic carbenes at ambient conditions
Authors: Sureshbabu, B.
Ramkumar, V.
Sankararaman, S.
Keywords: Palladation of meso-ionic
Issue Date: 2014
Publisher: Royal Society of Chemistry
Citation: Dalton Transactions, 43(28), 10710-10712
Abstract: Synthesis of normal and mesoionic N-heterocyclic carbene Pd(ii) complexes in near quantitative yields from the corresponding NHC precursor salts under base free and ambient conditions is reported. A plausible mechanism involving charge-assisted hydrogen bonded intermediates is proposed.
URI: http://dx.doi.org/10.1039/c4dt01112k
http://hdl.handle.net/11717/15515
ISSN: 14779226
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