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Title: Facile base-free in situ generation and palladation of mesoionic and normal N-heterocyclic carbenes at ambient conditions
Authors: Sureshbabu, B.
Ramkumar, V.
Sankararaman, S.
Keywords: Palladation of meso-ionic
Issue Date: 2014
Publisher: Royal Society of Chemistry
Citation: Dalton Transactions, 43(28), 10710-10712
Abstract: Synthesis of normal and mesoionic N-heterocyclic carbene Pd(ii) complexes in near quantitative yields from the corresponding NHC precursor salts under base free and ambient conditions is reported. A plausible mechanism involving charge-assisted hydrogen bonded intermediates is proposed.
ISSN: 14779226
Appears in Collections:Articles

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