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Title: Catalytic asymmetric hydrogenation using a [2.2]paracyclophane based chiral 1,2,3-triazol-5-ylidene-Pd complex under ambient conditions and 1 atmosphere of H2
Authors: Dasgupta, A.
Ramkumar, V.
Sankararaman, S.
Keywords: Hydrocarbons
Synthesis (chemical)
Ambient conditions
Asymmetric hydrogenation
Chemoselective hydrogenation
CO ligands
Enantioselective hydrogenation
Prochiral alkenes
Issue Date: 2015
Publisher: Royal Society of Chemistry
Citation: RSC Advances, 5(28), 21558-21561
Abstract: Chiral 1,2,3-triazol-5-ylidene-Pd complexes with the planar chiral [2.2]paracyclophane wing tip group have been synthesized and structurally characterized. The complex with a labile acetonitrile co-ligand is an excellent catalyst for chemoselective hydrogenation of alkynes and alkenes and enantioselective hydrogenation of prochiral alkenes at ambient conditions and 1.0 atmosphere of H2. � 2015 The Royal Society of Chemistry.
ISSN: 20462069
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