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|Title:||13C NMR and dielectric relaxation studies of methanol+nitrile systems|
|Citation:||Indian Journal of Pure and Applied Physics, 42(11), 837-840|
|Abstract:||13C NMR studies for both spin-lattice relaxation time (T 1) and chemical shifts were obtained for two systems namely methanol+acetonitrile and methanol+acrylonitrile. The dielectric dispersion data was also obtained for these systems. The 13C NMR and dielectric dispersion data with a view to understand the conformation of these systems and also to understand the basic mechanisms of relaxation in the same have been presented. A correlation between the rotational correlation time from NMR and the dielectric relaxation time for the two systems have been reported. The confirmation of the ring-like conformer for methanol+acetonitrile system using 13C NMR chemical shift data.|
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