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An Angular Coumarinacene and Its Characteristics

01-06-2021, Kumar, Abhinav, Venkatakrishnan P

This paper describes the synthesis of an angular coumarinacene. Its molecular structure by single-crystal X-ray analysis is revealed for the first time, which noted a sandwich-dimeric herringbone arrangement. Its solution reveals visible absorption and bright yellow-orange emission. The pyranone-annulated angular coumarinacene is relatively stable, both thermally and photochemically, when compared to popular acenes. Its alignment of frontier orbital energy levels dictates its possible entry into electronics.