Swaminathan Parasuraman

Printed electronics is an emerging field involving the fabrication of electronic devices by the patterned deposition of material inks. For many systems, producing stable printable inks is the key challenge. In this work, the formulation of a silver nanowire-based ink for printed transparent electrode applications is described. The nanowire length and rheology of the ink are adjusted for printing, with a single layer printed film having a sheet resistance of approximately 30 Ω/□ and a transmittance of 94% at 550 nm. The number of printed layers and volume per layer are optimized to get maximum transparency with good electrical conduction. A transparent capacitive touch pad, in the form of a 2 2 matrix is implemented, using this ink and with PDMS as the dielectric. The touch pad has a high degree of flexibility with a resistance variation less than 2% after 10 000 bending cycles. The formulated nanowire ink can be extended for other flexible and stretchable transparent sensing applications.

Patterned deposition of highly flexible transparent conducting materials is essential to realize stretchable optoelectronic devices. Silver nanowires (NWs) are suitable for these applications because they possess high electrical conductivity and good optical transparency. However, NWs have poor surface adhesion and large roughness. Embedding them in a conducting polymer, such as poly(3,4-ethylenedioxythiophene): polystyrene sulfonate (PEDOT:PSS), is one way to overcome these disadvantages without affecting the optoelectronic properties. However, this is normally a two-step deposition process and difficult to pattern directly. In this work, we have formulated a stable and printable nanocomposite ink consisting of Ag NWs and PEDOT:PSS. This ink can be directly used for patterned deposition in a single-step process. The printed film shows 86% transparency and 23 ω/sq sheet resistance, which is suitable for flexible transparent electrode applications. The printed film shows good adhesion and excellent stability to mechanical deformation, with less than 20% resistance variation after 10,000 bending cycles. The nanocomposite also exhibits improved thermal stability, planarity, reduced contact resistance, and good optical transparency when compared to pure Ag NWs. We demonstrate suitability of this nanocomposite using two applications -a printed transparent flexible antenna radiating at Wi-Fi frequencies and a printed transparent flexible heater suitable for antifogging applications. The nanocomposite properties make it suitable as a transparent electrode in flexible optoelectronic devices such as photovoltaics and light-emitting diodes.

Zinc oxide (ZnO) is widely used as an absorber layer in photodetectors (PDs). Here, we demonstrate a printed transparent PD with an absorber layer based on a nanocomposite of ZnO with silver nanowires (Ag NWs). The nanocomposite shows good optoelectronic properties; a single pass film exhibits 93% transparency at 550 nm and a low sheet resistance of 28.7 Ω sq-1, which allows for the device to operate at low voltages. Its formulation as printable ink with a low annealing temperature of 100 C makes it suitable for a single step patterned deposition and compatible with flexible substrates that cannot withstand higher temperature. Unlike conventional PDs, the photoconductivity decreases under illumination, i.e. the resistance of the nanocomposite is higher than in dark condition. This anomalous behavior can be explained based on the band alignment between ZnO and Ag in the nanocomposite. The Schottky barrier between ZnO and Ag prevents photo-generated electrons in ZnO from moving to the NWs, while the photo-generated holes recombine with the electrons flowing in the NWs leading to a resistance increase. The PD exhibits an improved photoresponsivity of 35 mA W-1, at a relatively low biasing voltage of 1 V, compared to a pure ZnO absorber layer with a responsivity of 14 mA W-1 at 5 V bias for an illumination at 365 nm. The properties of the nanocomposite make it suitable for single layer, low cost, and large area transparent PDs. The anomalous resistance change can also be extended to fabricating other kinds of sensors, such as gas or humidity sensors, with this nanocomposite.

Flexible, lightweight, low-power, and low-cost displays are an active area of interest in the electronics community. In this work, we have developed a composite electrothermochromic material consisting of silver nanowires (Ag NWs) and thermochromic powders, which exhibits reversible color (phase) change during biasing due to Joule heating. A wide variety of color combinations are possible with suitable thermochromic material selection. We have formulated this composite material as a printable ink so that patterned deposition can be achieved in a single step. A low processing temperature of 100 °C makes the composite compatible with a wide range of flexible substrates such as paper and polyethylene terephthalate (PET). The material (encapsulated with polydimethylsiloxane (PDMS)) exhibits good flexibility and is observed to be functional after 10 000 bending cycles with <7% resistance change. We have fabricated a low-power seven-segment color display to show the material's suitability for practical display applications. We have also demonstrated that the same layer can function as a display and as a touch sensor because of its conducting and chromatic properties without additional active layers on top. The material is suitable for the fabrication of low-cost, flexible touch color displays for interactive electronic readers, digital posters, and flexible digital signboards.