Publication: Halogenative kinetic resolution of β-amido alcohols: Chiral BINAP-mediated S<inf>N</inf>2 displacement of hydroxy groups by chlorides with inversion of stereochemistry
cris.author.scopus-author-id | 15848148800 | |
cris.author.scopus-author-id | 6602184820 | |
cris.virtual.author-orcid | 0000-0003-2294-0485 | |
cris.virtual.author-orcid | #PLACEHOLDER_PARENT_METADATA_VALUE# | |
cris.virtual.department | Indian Institute of Technology, Madras | |
cris.virtual.department | #PLACEHOLDER_PARENT_METADATA_VALUE# | |
cris.virtualsource.author-orcid | a77c338c-b73c-4dcc-89ee-e0affae516e5 | |
cris.virtualsource.author-orcid | #PLACEHOLDER_PARENT_METADATA_VALUE# | |
cris.virtualsource.department | a77c338c-b73c-4dcc-89ee-e0affae516e5 | |
cris.virtualsource.department | #PLACEHOLDER_PARENT_METADATA_VALUE# | |
dc.contributor.author | Jaseer, E. A. | |
dc.contributor.author | G Sekar | |
dc.date.accessioned | 2023-09-20T05:25:32Z | |
dc.date.available | 2023-09-20T05:25:32Z | |
dc.date.issued | 21-04-2010 | |
dc.description.abstract | A series of optically active cyclic trans-β-amido alcohols were obtained by the non-enzymatic kinetic resolution of the corresponding racemic amido alcohols using commercially available (S)-BINAP and NCS by SN2 halogenation of the hydroxy group. The product, cis-β-amido chloride, was also obtained in optically active form with an inversion of stereochemistry. © 2010 Elsevier Ltd. All rights reserved. | |
dc.identifier.doi | 10.1016/j.tetasy.2010.04.011 | |
dc.identifier.issn | 9574166 | |
dc.identifier.scopus | 2-s2.0-77956189284 | |
dc.identifier.uri | https://apicris.irins.org/handle/IITM2023/44095 | |
dc.relation.ispartofseries | Tetrahedron Asymmetry | |
dc.source | Tetrahedron Asymmetry | |
dc.title | Halogenative kinetic resolution of β-amido alcohols: Chiral BINAP-mediated S<inf>N</inf>2 displacement of hydroxy groups by chlorides with inversion of stereochemistry | |
dc.type | Journal | |
dspace.entity.type | Publication | |
oaire.citation.endPage | 785 | |
oaire.citation.issue | 7 | |
oaire.citation.startPage | 780 | |
oaire.citation.volume | 21 | |
oairecerif.author.affiliation | #PLACEHOLDER_PARENT_METADATA_VALUE# | |
oairecerif.author.affiliation | Indian Institute of Technology, Madras | |
person.affiliation.city | Chennai | |
person.affiliation.id | 60025757 | |
person.affiliation.name | Indian Institute of Technology Madras |