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Cu-Catalyzed one-pot synthesis of thiochromeno-quinolinone and thiochromeno-thioflavone: Via oxidative double hetero Michael addition using in situ generated nucleophiles
Date Issued
11-08-2020
Author(s)
Sundaravelu, Nallappan
Indian Institute of Technology, Madras
Abstract
A copper catalyzed three-component synthesis of π-conjugated tetracyclic thiochromeno-quinolinone and thiochromeno-thioflavone was established via oxidative double hetero Michael addition using in situ generated nucleophiles. Xanthate plays a dual role as an odourless sulfur source and a chemoselective reducing agent. The in situ formed iodine plays a crucial role in the oxidation step. This journal is
Volume
56