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Recent progress in production of infiltration-growth and melt-growth processed bulk (RE)Ba<inf>2</inf>Cu<inf>3</inf>O<inf>y</inf>
Date Issued
01-07-2020
Author(s)
Muralidhar, M.
Sunsanee, P.
Takemura, K.
Sai Srikanth, A.
Jirsa, M.
Indian Institute of Technology, Madras
Oka, T.
Sakai, N.
Murakami, M.
Abstract
Novel methods are necessary to further increase the critical current density (Jc ) and uniformity of (RE)Ba2Cu3Oy (RE-123; RE - rare earth element) materials. In this contribution we address several issues of infiltration growth (IG) and melt-growth (MG) processing of RE-123 bulks and show recent progress: (i) optimization of 211 composition in IG-processed mixed YGd system type for the production of good-performance RE-123 bulks (RE: YGd), (ii) optimization of the thermal profile in IG processing of a mixed YEr-123 system for producing large bulks, and (iii) preparation of sharp-edge refined RE-211-phase particles by means of a high-energy ultra-sonication to improve performance of MG-processed Y-123. All products were studied by means of SQUID, SEM, TEM, and trapped field measurements at liquid nitrogen temperature. Our experimental results indicate that in an IG-processed mixed YGd-123 system, Y:Gd = 75:25 is the best ratio for optimum performance. In a YEr (Y:Er = 90:10) system, a series of isothermal experiments revealed that 990 C is the optimum temperature for maximum growth and performance. On the other hand, in the MG-processed bulk, the Y-211-phase particles exposed to ultra-sonic energy of 300 W for 80 min are smaller than those produced by a conventional process, mainly due to shearing and high-speed collisions of particles. As a result, a doubled-trapped field was achieved at 77 K as compared to traditional reference bulk. We will summarize the improved electromagnetic properties of IG- and MG-processed RE-123 bulks and their relation to microstructure changes in the final products.
Volume
33