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Indium trichloride catalyzed glycosidation. An expeditious synthesis of 2,3-unsaturated glycopyranosides
Date Issued
19-02-2000
Author(s)
Sobhana Babu, Boga
Kuppuswamy Balasubramanian, Kalpattu
Abstract
Treatment of tri-O-acetyl-D-glucal 1 with various alcohols and phenols in the presence of InCl3/CH2Cl2 at ambient temperature gave the corresponding alkyl and aryl 2,3-unsaturated glycopyranosides in excellent yields with short reaction times and good anomeric selectivity. (C) 2000 Elsevier Science Ltd.
Volume
41