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  1. Home
  2. Indian Institute of Technology Madras
  3. Publication7
  4. Rhodium catalyzed cyanation of chelation assisted C-H bonds
 
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Rhodium catalyzed cyanation of chelation assisted C-H bonds

Date Issued
04-10-2013
Author(s)
Chaitanya, Manthena
Yadagiri, Dongari
Pazhamalai Anbarasan 
Indian Institute of Technology, Madras
DOI
10.1021/ol402201c
Abstract
A rhodium-catalyzed cyanation of chelation assisted C-H bonds is described employing N-cyano-N-phenyl-p-methylbenzenesulfonamide as an efficient cyanating reagent. The present method allowed the synthesis of various benzonitirle derivatives in good to excellent yield. A number of chelating groups are also effective in the present cyanation of C-H bonds. In addition, the developed methodology was applied in the formal synthesis of the isoquinoline alkaloid, menisporphine. © 2013 American Chemical Society.
Volume
15
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