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A novel heterometallic μ<inf>9</inf>-boride cluster: Synthesis and structural characterization of [(η<sup>5</sup>-C<inf>5</inf>Me <inf>5</inf>Rh)<inf>2</inf>{Co<inf>6</inf>(CO)<inf>12</inf>}(μ-H)(BH)B]
Date Issued
21-01-2014
Author(s)
Roy, Dipak Kumar
Barik, Subrat Kumar
Mondal, Bijan
Varghese, Babu
Indian Institute of Technology, Madras
Abstract
The preparation, characterization, and electronic structure of the first heterometallic μ9-boride cluster [(Cp*Rh) 2{Co6(CO)12}(μ-H)(BH)B)] has been reported. The interstitial boron atom in the title cluster is within the bonding contact of eight metal and one boron atom in a unique tricapped trigonal prism geometry. © 2013 American Chemical Society.
Volume
53