Dipotassiumtetrachloride-bridged dysprosium metallocenes: a single-molecule magnet

The present work describes the dynamic magnetic properties of the complex [(CpAr3)4DyIII2Cl4K2]·3.5(C7H8) (1), synthesized by employing a tri-aryl-substituted cyclopentadienyl ligand (CpAr3), [4,4′-(4-phenylcyclopenta-1,3-diene-1,2-diyl)bis(methylbenzene) = CpAr3H]. Each Dy(iii)-metallocene weakly couples via K2Cl4, displaying slow relaxation of magnetization below 14.5 K under zero applied dc field via KD3 energy levels with an energy barrier of 136.9/133.7 cm−1 on the Dy sites. The single-ion axial anisotropy energy barrier is reduced by geometrical distortion due to the coordination of two chloride ions at each Dy centre.