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  1. Home
  2. Indian Institute of Technology Madras
  3. Publication5
  4. Cp*Co(iii)-catalysed selective alkylation of C-H bonds of arenes and heteroarenes with α-diazocarbonyl compounds
 
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Cp*Co(iii)-catalysed selective alkylation of C-H bonds of arenes and heteroarenes with α-diazocarbonyl compounds

Date Issued
01-01-2018
Author(s)
Ghorai, Jayanta
Chaitanya, Manthena
Anbarasan, Pazhamalai 
Indian Institute of Technology, Madras
DOI
10.1039/c8ob02111b
Abstract
Cp*Co(iii)-catalysed selective alkylation of directed C-H bonds of arenes and heteroarenes has been accomplished employing donor-acceptor carbenes, derived from α-diazocarbonyl compounds. The developed method allows ready access to various substituted α-(hetero)aryl-α-arylacetic acid derivatives in good to excellent yields. Synthetic utility was also shown through the synthesis of a substituted indole derivative, an anticancer agent.
Volume
16
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