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  1. Home
  2. Indian Institute of Technology Madras
  3. Publication6
  4. CBr<inf>4</inf> as a Halogen Bond Donor Catalyst for the Selective Activation of Benzaldehydes to Synthesize α,β-Unsaturated Ketones
 
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CBr<inf>4</inf> as a Halogen Bond Donor Catalyst for the Selective Activation of Benzaldehydes to Synthesize α,β-Unsaturated Ketones

Date Issued
03-03-2017
Author(s)
Kazi, Imran
Guha, Somraj
G Sekar 
Indian Institute of Technology, Madras
DOI
10.1021/acs.orglett.7b00348
Abstract
CBr4 has been employed as a halogen bond donor catalyst for the selective activation of aldehyde, to achieve an efficient solvent- and metal-free CC bond forming reaction in the presence of strong acid sensitive groups such as methoxy, cyanide, ester, and ketal for the synthesis of α,β-unsaturated ketones. This unique capability of CBr4 to act as a halogen bond donor has been explored and established using UV-vis as well as IR spectroscopy. Moreover, this unprecedented methodology enables the synthesis of the pharmaceutically important molecule licochalcone A.
Volume
19
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