Growth and characterization of a new nonlinear optical material: Potassium p-nitrophenolate dihydrate (NO<inf>2</inf>-C<inf>6</inf>H<inf>4</inf>- OK·2H<inf>2</inf>O) with new bonding properties

Single crystals of potassium p-nitrophenolate dihydrate (NPK·2H 2O) have been grown successfully using the isothermal solvent evaporation technique. It is a new semiorganic nonlinear optical crystal, possessing a deff of about 1.5 times that of lithium niobate and in which the K+ ions are bonded to the nitro group instead of bonding with the phenolic O-. Large single crystals of dimension upto 20×6×4 mm3 are harvested within a period of 60 days. The grown crystals are subjected to single crystal X-ray, FTIR and DRS-UV visible spectral, thermal and microhardness analyses. Single crystal X-ray analysis confirms the molecular formula and the structure of the crystal. FTIR spectral studies verify the functional groups present in the crystal. The DRS-UV visible spectrum proved the optical transparency of the crystal in the entire visible and near infrared region. Thermal studies reveal that the crystals are stable upto 180 °C. Microhardness measurements on the cleaved plane (1 1 0) explain the strength and slip direction in the crystal. The SHG efficiency of the crystal is examined by performing the Kurtz powder test using Nd:YAG laser. © 2005 Elsevier B.V. All rights reserved.