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A fine tuning of metallaborane to bridged-boryl complex, [(Cp*Ru)<inf>2</inf>(μ-H)(μ-CO)(μ-Bcat)] (cat = 1,2-O<inf>2</inf>C<inf>6</inf>H<inf>4</inf>; Cp* = η<sup>5</sup>-C<inf>5</inf>Me<inf>5</inf>)
Date Issued
20-08-2013
Author(s)
Anju, R. S.
Roy, Dipak Kumar
Geetharani, K.
Mondal, Bijan
Varghese, Babu
Indian Institute of Technology, Madras
Abstract
Room temperature photolysis of [(Cp*RuCO)2BH4(Bcat)], 3, generated from the reaction of arachno-[(Cp*RuCO)2B2H6], 1, with HBcat (cat = 1,2-O2C6H4), yielded a rare homodinuclear bridged-boryl complex, [(Cp*Ru)2(μ-H)(μ-CO)(μ-Bcat)], 4, confirmed by X-ray diffraction. © 2013 The Royal Society of Chemistry.
Volume
42