Performance characterization of geopolymer composites for hot sodium exposed sacrificial layer in fast breeder reactors

A sacrificial layer of concrete is used in sodium cooled fast breeder reactors (SCFBRs) to mitigate thermo-chemical effect of accidentally spilled sodium at and above 550 C on structural concrete. Performance of this layer is governed by thermo-chemical stability of the ingredients of sacrificial layer concrete. Concrete with limestone aggregate is generally used as a sacrificial layer. Conventional cement based systems exhibit instability in hot liquid sodium environment. Geo-polymer composites are well known to perform excellently at elevated temperatures compared to conventional cement systems. This paper discusses performance of such composites subjected to exposure of hot liquid sodium in air. The investigation includes comprehensive evaluation of various geo-polymer composites before any exposure, after heating to 550 C in air, and after immersing in hot liquid sodium initially heated to 550 C in air. Results from the current study indicate that hot liquid sodium produces less damage to geopolymer composites than to the existing conventional cement based system. Hence, the geopolymer technology has potential application in mitigating the degrading effects of sodium fires and can emerge as a new choice for sodium exposed sacrificial layer in SCFBRs. © 2013 Elsevier B.V. All rights reserved.