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STRUCTURE OF BIS(DIETHYLDITHIOCARBAMATO)DIIODOTELLURIUM(IV)
Date Issued
1993
Author(s)
KUMAR, RK
ARAVAMUDAN, G
UDUPA, MR
SESHASAYEE, M
HAMOR, TA
Abstract
Centrosymmetric dimers are formed in the structure through two I atoms bridging two Te atoms. Te is seven-coordinated, bound to four S atoms, two intramolecular axial I atoms and one intermolecular planar bridging I atom, in a distorted pentagonal bipyramidal geometry. The non-bridging I atoms in the dimer have a secondary interaction with similar I atoms of other dimers.
Volume
49