Three-Phase Fluid Flow Interaction at Pore Scale during Water- and Surfactant-Alternating Gas (WAG/SAG) Injection Using Carbon Dioxide for Geo-Sequestration and Enhanced Oil Recovery

Sequestration of CO2 in geologic formations such as depleted oil reservoirs has emerged as one of the lead solutions to tackle greenhouse gas emissions to reduce pollution and global warming. Supercritical CO2 (sc-CO2) injection in oil reservoirs has proven to be useful as an enhanced oil recovery (EOR) technique along with the benefits of CO2 sequestration. In this study, a tortuous microscopic pore scale model was used to study and investigate the phenomena of water-alternating gas (WAG) and surfactant-alternating gas (SAG) with sc-CO2. The study scrutinizes the dynamics of the pore-level phenomenon in the multiphase WAG and SAG flows at the pore level in detail. Transient computational fluid dynamics (CFD) analysis was used to study the fluid flow characteristics of oil, water, and sc-CO2 at different reservoir pressure and temperature conditions in oil-wet conditions. Governing equations were coupled with EOS (Helmholtz free energy equation) to capture the viscous and intrinsic properties of sc-CO2 due to variations in pressure and temperature conditions. It was found that higher oil recovery does not necessarily indicate higher sc-CO2 sequestration and that temperature harms the displacement mechanism due to unfavorable mobility ratios. Comparing WAG and SAG for the first injection cycle, SAG showed a more diffused interface between displaced and displacing fluid. The additional oil recovery produced in patches was a result of pressure oscillations near the blind pores. Moreover, high vorticity promotes greater intermixing between the displacing and displaced fluid by increasing the rate of interface length. In SAG cases, faster sc-CO2 breakthroughs were observed due to reduced shear stress along the fluid interfaces, which resulted in higher sequestration values in a given time frame. The CO2 sequestration volume in SAG cases was found to be approximately 40% more than in WAG experiments. The study confirms that lower values of oil-water interfacial tension aids in faster and more efficient sequestration of sc-CO2 along with additional oil gain from a given reservoir.