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Effect of short-term sulphate contamination on lime-stabilized expansive soil
Date Issued
01-01-2021
Author(s)
Sriram Karthick Raja, P.
Indian Institute of Technology, Madras
Abstract
Lime stabilization is an age-old technique for controlling the swell-shrink characteristics of the expansive soil. However, the presence of sulphate in the expansive soils renders the lime stabilization ineffective due to the formation of detrimental compounds–ettringite and thaumasite. The formation of these detrimental compounds can be counteracted by treatment with low-calcium or non-calcium based stabilizers. However, there is a possibility of sulphate contamination post lime stabilization through external sources. Therefore, the present study brings out the effect of short-term sulphate contamination on lime-stabilized expansive soil using sodium sulphate solution. To achieve this objective, the lime-stabilized expansive soil was cured for 1, 7 and 28 days, and subsequently mixed with sulphate solutions of 5000–20,000 ppm concentration and allowed to equilibrate for 1 day. The experimental results showed that the sulphate contamination had a significant effect on the soil structure, physico-chemical and index properties of lime-stabilized soil. The mechanism governing the deterioration of the stabilized soil depended on the curing period of lime-stabilized soil prior to contamination with sulphate. Short-term sulphate contamination of lime-stabilized soil cured for 1 and 7 days resulted in highly flocculated structure, whereas the lime-stabilized soil cured for 28 days resulted in the formation of ettringite. This is evidenced with the aid of Scanning Electron Microscopy (SEM) images, X-ray diffraction (XRD) and Energy Dispersive X-Ray Analysis (EDAX). It can be concluded from this study that the ettringite formation occurs even after the formation of pozzolanic compounds in lime-stabilized soil.
Volume
15