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Hetero Diels-Alder reaction of olefin with o-quinone methides generated using (±)-binolphosphoric acid for the stereoselective synthesis of 2,4-diarylbenzopyrans: Application to the formal synthesis of myristinin B/C
Date Issued
28-10-2013
Author(s)
Gharpure, Santosh J.
Sathiyanarayanan, A. M.
Vuram, Prasanna K.
Abstract
Hetero Diels-Alder reaction of olefin with o-quinone methides (o-QMs) generated using (±)-binolphosphoric acid was developed for the stereoselective synthesis of 2,4-diarylbenzopyrans. The method thus developed was utilized in the formal synthesis of myristinin B/C. © 2013 The Royal Society of Chemistry.
Volume
3