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Dichloro[2,2-diphenyl-4,4,6,6-tetrakis(3,5-dimethyl-pyrazol-1-yl)cyclotriphosphazene]cobalt(II)
Date Issued
2001
Author(s)
Prabakaran, P
Thomas, KRJ
Muthiah, PT
Bocelli, G
Righhi, L
Abstract
The title compound, [N3P3(C5H7N2)(4)(C6H5)(2)]CoCl2 or [CoCl2(C32H38N11P3)], possesses a five-coordinated Co-II atom in an approximately trigonal-bipyramidal geometry. The N3Cl2 donor set of the metal environment comprises two nongeminal pyrazolyl N atoms, one cyclotriphosphazene N atom, and two Cl- ions. The coordination environment and bonding features of the compound are critically compared with related metal complexes of cyclotriphosphazene ligands.
Volume
57