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A homometallic tricapped cubane cluster: [(Cp*Mo) <inf>4</inf>B <inf>4</inf>H <inf>4</inf>(μ <inf>4</inf>-BH) <inf>3</inf>] (Cp* = η <sup>5</sup>-C <inf>5</inf>Me <inf>5</inf>)
Date Issued
05-09-2011
Author(s)
Abstract
The reaction of [Cp*MoCl 4] with an excess of LiBH 4, followed by thermolysis with tellurium powder in toluene, afforded a tricapped cubane cluster, [(Cp*Mo) 4B 4H 4(μ 4-BH) 3] (1), which represents an unprecedented metal-rich metallaborane cluster with a cubane core containing 58 cluster valence electrons (cve) and three metal-metal bonds. © 2011 American Chemical Society.
Volume
50