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Pt nanoparticle-dispersed graphene-wrapped MWNT composites as oxygen reduction reaction electrocatalyst in proton exchange membrane fuel cell
Date Issued
22-08-2012
Author(s)
Aravind, S. S.Jyothirmayee
Indian Institute of Technology, Madras
Abstract
Chemical and electrical synergies between graphite oxide and multiwalled carbon nanotube (MWNT) for processing graphene wrapped-MWNT hybrids has been realized by chemical vapor deposition without any chemical functionalization. Potential of the hybrid composites have been demonstrated by employing them as electrocatalyst supports in proton exchange membrane fuel cells. The defects present in the polyelectrolyte, which have been wrapped over highly dispersed MWNT, act as anchoring sites for the homogeneous deposition of platinum nanoparticles. Single-cell proton exchange membrane fuel cells show that the power density of the hybrid composite-based fuel cells is higher compared to the pure catalyst-support-based fuel cells, because of enhanced electrochemical reactivity and good surface area of the nanocomposites. © 2012 American Chemical Society.
Volume
4