Dillip K Satapathy

Hypothesis: Spray drying is a facile technique to transform colloidal dispersion into micro-granules of controlled size, shape, and morphology. There is significant interest to understand the structural integrity, different morphology of the granules obtained post spray drying which find potential application in many technological fields. The shape of the constituent particles in the colloidal dispersion that is spray dried is expected to influence the micro-structural features of the micro-granules. Experiments: We investigate the formation of micro-granules consisting of nano-ellipsoids through controlled spray drying. The morphological features and the packing of ellipsoids in the granules are quantitatively analyzed by using small angle neutron scattering, small angle X-ray scattering and high-resolution field emission scanning electron microscopy. The time evolution of the micro-structure and the structural integrity of the granules are investigated by re-dispersing the powder granules in water. Findings: The morphology of the granules are found to be strongly correlated with the aspect ratio of the ellipsoid. While the drying of droplets containing lower aspect ratio ellipsoids give rise to mostly spherical granules, in stark contrast, for higher aspect ratio ellipsoids, micro-granules of different morphologies are formed including doughnut shaped granules. A plausible mechanism explaining such an aspect ratio dependent shape transformation is proposed.

Hypothesis: Microgels are a class of model soft colloids that act like surfactants due to their amphiphilicity and are spontaneously adsorbed to the fluid-air interface. Here, we exploit the surfactant-like characteristics of microgels to generate Marangoni stress-induced fluid flow at the surface of a drop containing soft colloids. This Marangoni flow combined with the well-known capillary flow that arises during the evaporation of a drop placed on a solid surface, leads to the formation of a novel two-dimensional deposit of particles with distinct depletion zones at its edge. Experiments: The evaporation experiments using sessile and pendant drops containing microgel particles were carried out, and the microstructure of the final particulate deposits were recorded. The kinetics of the formation of the depletion zone and its width is studied by tracking the time evolution of the microgel particle monolayer adsorbed to the interface using in situ video microscopy. Findings: The experiments reveal that the depletion zone width linearly increases with droplet volume. Interestingly, the depletion zone width is larger for drops evaporated in pendant configuration than the sessile drops, which is corroborated by considering the gravitational forces exerted on the microgel assembly on the fluid-air interface. The fluid flows arising from Marangoni stresses and the effect of gravity provide novel ways to manipulate the self-assembly of two-dimensional layers of soft colloids.