Repository logo
  • English
  • Català
  • Čeština
  • Deutsch
  • Español
  • Français
  • Gàidhlig
  • Italiano
  • Latviešu
  • Magyar
  • Nederlands
  • Polski
  • Português
  • Português do Brasil
  • Suomi
  • Svenska
  • Türkçe
  • Қазақ
  • বাংলা
  • हिंदी
  • Ελληνικά
  • Yкраї́нська
  • Log In
    or
    New user? Click here to register.Have you forgotten your password?
Repository logo
  • Communities & Collections
  • Research Outputs
  • Fundings & Projects
  • People
  • Statistics
  • English
  • Català
  • Čeština
  • Deutsch
  • Español
  • Français
  • Gàidhlig
  • Italiano
  • Latviešu
  • Magyar
  • Nederlands
  • Polski
  • Português
  • Português do Brasil
  • Suomi
  • Svenska
  • Türkçe
  • Қазақ
  • বাংলা
  • हिंदी
  • Ελληνικά
  • Yкраї́нська
  • Log In
    or
    New user? Click here to register.Have you forgotten your password?
  1. Home
  2. Indian Institute of Technology Madras
  3. Publication12
  4. Ortho effects in organic molecules on electron impact. 14—Concerted and stepwise ejections of SO<inf>2</inf> and N<inf>2</inf> from N†arylidene 2†nitrobenzenesulphenamides
 
  • Details
Options

Ortho effects in organic molecules on electron impact. 14—Concerted and stepwise ejections of SO<inf>2</inf> and N<inf>2</inf> from N†arylidene 2†nitrobenzenesulphenamides

Date Issued
01-01-1987
Author(s)
Ramana, D. V.
Sundaram, N.
George, M.
DOI
10.1002/oms.1210220305
Abstract
Unexpected ortho interaction of the nitro group has been noticed during the mass spectral fragmentations of N‐arylidene 2‐nitrobenzenesulphenamides, where the molecular ions expel SO2 and N2 both in concerted and stepwise processes. Loss of a hydrogen or the substituent from this fragment leads to a very abundant ion in all the compounds studied. Based on chemical evidence and linked‐scan studies, a 1,2‐phenylenetropylium cation structure has been postulated for the [M–SO2–N2–H/substituent]+ ion. Copyright © 1987 John Wiley & Sons, Ltd.
Volume
22
Indian Institute of Technology Madras Knowledge Repository developed and maintained by the Library

Built with DSpace-CRIS software - Extension maintained and optimized by 4Science

  • Cookie settings
  • Privacy policy
  • End User Agreement
  • Send Feedback